Yeah, since steel shot is categorized as "surface enhancement" rather than cleaning like glass bead is often used for, I wouldn't shot peen the valves either. If you're still looking to clean your valves, I still think a glass bead cleaning would work.
(if it makes any difference: I'm a manufacturing engineer for a company that makes case-hardened aerospace gears & shafts. We use glass bead on nearly every part we manufacture. It's been proven not to degrade the surface of the base metal, but still maintains cleaning qualities.)



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